freeze is right, not bulldog.
Think about the odds of rolling a pair. there are 6 ways to do it, and 36 possible rolls, so 1/6 chance of rolling a pair. Its a 1/36, that is 1/(6*6) probability of rolling a SPECIFIC pair. If you have N dice, it's 6^(N-1) OR (6^N)/6 (divide by 6 because it can be any one of the pairs).
So, the probability is 1/1296, or 1295-1 against it happening.